Molecular 'Elbow Room' Unlocks Faster, Heat-Resistant Optical Tech
Source PublicationAdvanced Science
Primary AuthorsGe, Huo, Liu et al.

Engineers building next-generation optical devices face a persistent challenge: creating materials that are both highly efficient and stable at high temperatures. Researchers have now synthesised a solution by designing four new organic molecules, called chromophores, with a crucial modification. They incorporated bulky chemical groups into the molecular structure.
These attachments provide 'steric hindrance', acting like built-in spacers that stop the molecules from crowding too closely. This forced separation not only enhances their long-term alignment but also significantly boosts their thermal stability, withstanding temperatures above 130°C.
One molecule, BHG2, proved exceptional. It self-assembled into a high-quality film and, when used to build an electro-optic modulator—a device that converts electrical signals to optical ones—it demonstrated a data bandwidth exceeding 40 GHz. This work signals a major step towards creating powerful and practical optoelectronic components.