Magnetic Surprise: Simple Duo Could Forge Powerful New Magnets
Source PublicationJournal of the American Chemical Society
Primary AuthorsBadding, Puggioni, Yang et al.

In the quest for new materials, sometimes the simplest combinations hide the most surprising behaviour. Researchers have explored the binary system of cobalt, a known magnetic element, and bismuth, the heaviest stable element. This chemical duo was already known to exhibit superconductivity under certain conditions, but scientists hypothesised it could also be ferromagnetic, a key property of permanent magnets.
Using powerful computer modelling, the team predicted the existence of five new cobalt-bismuth (Co-Bi) compounds. They then tested these predictions in the lab, using high-pressure synthesis to successfully create four new materials. Remarkably, three of these matched the computer-predicted structures, demonstrating the power of this combined theoretical and experimental approach.
Crucially, the modelling predicts that two of the new forms, β-CoBi and β-CoBi2, are ferromagnetic. One of them, β-CoBi, is even predicted to have a greater magnetocrystalline anisotropy—a measure of its ability to resist demagnetisation—than some familiar permanent magnets. This work establishes the simple Co-Bi system as an exciting platform for understanding the foundations of both magnetism and superconductivity.